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Electrochemical Activation of Catalysis: Promotion, Electrochemical Promotion, and Metal-Support Interactions
Electrochemical Activation of Catalysis: Promotion, Electrochemical Promotion, and Metal-Support Interactions
Date: 18 February 2011, 07:26

Electrochemical promotion, or non-Faradaic Electrochemical Modification of Catalytic Activity (NEMCA) came as a rather unexpected discovery in 1980 when with my student Mike Stoukides at MIT we were trying to influence in situ the rate and selectivity of ethylene epoxidation by fixing the oxygen "activity" on a Ag catalyst film deposited on a ceramic O2" conductor via electrical potential application between the catalyst and a counter electrode. Since then Electrochemical Promotion of Catalysis has been proven to be a general phenomenon at the interface of Catalysis and Electrochemistry. More than seventeen groups around the world have made important contributions in this area and this number is reasonably expected to grow further as the phenomenon of electrochemical promotion has very recently been found, as analyzed in this book, to be intimately related not only to chemical (classical) promotion and spillover, but also to the "heart" of industrial catalysis, i.e. metal-support interactions of classical supported catalysts.


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