Electrochemical Phase Fomation and Growth: An Introduction to the Initial Stages of Metal Deposition - ISBN:3527294228

Electrochemical Phase Fomation and Growth: An Introduction to the Initial Stages of Metal Deposition

Date: 13 April 2011, 16:47

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This book is a result of a collaboration by the authors over a long period of time. It is devoted to fundamental problems of electrochemical metal deposition. The first part gives an introduction to electrocrystallization. The second part describes structure, morphology, and reconstruction of solid metal surfaces treated as crystalline sub strates including the dynamic behavior of surface atoms. The third part treats surface modification by underpotential deposition (UPD) of metals. Physical nature, thermodynamics, structural aspects, kinetics, as well as surface alloy formation are discussed. Experimental support is given based on classical electrochemical investigations as well as on some recent results from modern in situ surface analytical studies including atomic imaging by in situ STM and AFM. In the fourth part of the book the problem of three-dimensional phase formation and growth by overpotential deposition (OPD) is presented. Thermodynamic and kinetic aspects are considered. The atomistic approach is discussed and illustrated on bare and UPD modified substrates.

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