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Sulfur-Mediated Rearrangements II (Topics in Current Chemistry) (v. 2)
Sulfur-Mediated Rearrangements II (Topics in Current Chemistry) (v. 2)
Date: 04 June 2011, 05:07

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In their analysis of experiments and in their planning of syntheses, organic chemists consciously or unconsciously tend to use the principle of least motion, the chemical equivalent of Occam’s razor. In rearrangement reactions this principle is violated and may make rearrangements problematic reactions. At the same time, there is always fascination in the unexpected and so rearrangement reactions are also an attractive field of study. Consequently, our understanding of rearrangement reactions is now quite advanced and allows strategic uses in organic synthesis. Here, a helpful tool that may easily be overlooked is the influence of organosulfur functionalities on these rearrangements. In fact, the presence of sulfur may make rearrangements predictable and productive or allow specific transformations which would otherwise require a tedious synthetic detour. The present account is meant to spread this knowledge. In addition, an introductory chapter gives a survey of the basics of organosulfur chemistry to put the information in the individual chapters into perspective and to help readers who are less familiar with the peculiarities of sulfur in an organic environment.
The amount of material requiring coverage was sovast that the volume had to be split into two parts.We hope that readers will appreciate the comprehensive and up-to-date information on sulfur-mediated rearrangements. Fortunately, leading experts were available to write the individual chapters and provide state-of-the-art reviews of the current research on sulfur-mediated rearrangements.
It was a pleasure to work with these colleagues and I appreciate their involvement in spite of many other obligations. This volume should help the chemical community in their synthetic work and so it was worth the effort.

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