Statistical Mechanics (McGraw Hill series in advanced chemistry)
Date: 21 April 2011, 02:41
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Preface The statistical mechanics of dilute systems of independent particles at equilibrium is a subject which is essentially fully developed. The practicing chemist should be able to apply this theory with assurance and accuracy to calculate the thermodynamic properties of substances in the ideal-gas state from molecular structure data. My first objectives have been to develop this theory in a simple, logical, and understandable way, and to describe the applications in sufficient detail, with illustrative problems, so that .the reader can acquire the desired skill in this elementary part of the subject. In the latter part of the book, I have tried to give a simple but rigorous account of the theories of the canonical ensemble and of the grand ensemhle for treating systems of interacting particles. Several rather elementary but important examples are then studied, to illustrate the applications of these general theories. The most prominent and important manifestation. of .fluctuatlon phenomena for the experimental scientist is noise. I have therefore included a discussion of this topic in the chapter on fluctuations. However, I have not included a serious discussion of practical theories of liquids and dense gases. This is an important topic in statistical mechanics but it is difficult and complicated. The theoretical calculations do not as yet give good agreement with experiment. There are several excellent treatises by experts in the field, and I prefer to refer the interested student to this literature. I hope that I have carried the theory of systems of interacting particles far enough to provide a good foundation for such further study. In addition, the latter half of the book presents discussions of some topics-paramagDetism, dielectrics, and ionic solutions-essentially from the point of view of. the statistical mechanics of independent particlesbut with at least an· indication of how the theories of the canonical ensemble and the grand ensemble can be applied when interparticle interactions · are importa;nt: This text has developed from my lecture notes for a one-year graduate course at the California Institute. Many of the students are first-year graduate students (with an occasional bright senior) who have not had a serious course in quantum mechanics, although they are usually takmg such a course simultaneously. I have therefore included a chapter which is an introductory discussion of the relevant parts of quantum mechanics. Fortunately, the principles of equilibrium statistical mechanics can be developed very satisfactorily on the basis of an elementary and unsophisticated formulation of quantum mechanics...
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