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Molecular Symmetry
Molecular Symmetry
Date: 14 April 2011, 02:21

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Symmetry is central to spectroscopy, chemical bonding theory and many other aspects of the molecular sciences. The idea of this book is to introduce the topic in a graduated way, from molecular structure, through point groups, leading into the powerful tools that group theory provides. Example models and applications are used at all stages to show how the sometimes abstract ideas are relevant to practical problems. It is designed to be a useful companion at all levels of undergraduate study and beyond. Chapters 1 and 2 introduce the ideas of symmetry elements and operations for the description of molecular geometry; this sets up the required symbols through examples of particular molecules. Chapter 3 looks from a slightly different perspective, laying out all the sets of operations that are contained in the common point groups and discussing why only certain sets are possible. For all three chapters Appendices 1, 2 and 4 give some paper models that can be used for visualization of the shapes that are not easily built using a molecular modeling kit. These paper models will also be available from the website. The reader interested in the applications of symmetry, without too much detail of the background, may wish to skip over Chapter 3 on the first reading. Chapters 4 and 5 introduce the concepts of group theory, which makes symmetry indispensible for understanding many areas of chemistry. This book concentrates on applications in vibrational spectroscopy and molecular orbital theory and so illustrative examples are drawn from these areas.

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