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Handbook of Metathesis
Handbook of Metathesis
Date: 13 April 2011, 04:25

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Not only did Ziegler’s discovery of metal-catalyzed olefin polymerizations forever change polymer science, but also the science surrounding it supplied the motivation for many areas of modern organometallic chemistry research [1]. Out of the explorations into new catalysts for the addition polymerization of olefins came a new type of catalyst, one that produced unsaturated polymers from cyclic olefins and ethylene-propylene copolymers from a simple propylene feed. It took a considerable amount of time, however, for researchers to realize that these two, apparently different, reactions were the same and that they represented a fundamentally new reaction.

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