Aqueous organometallic catalysis - ISBN:1402001959

Aqueous organometallic catalysis

Date: 14 April 2011, 02:21

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Aqueous organometallic catalysis is a rapidly developing field and there are several reasons for the widespread interest. Perhaps the most important is the possibility of using liquid-liquid two-phase systems for running catalytic reactions. Often termed liquid biphasic catalysis, these two-phase procedures allow recycling of the catalyst dissolved exclusively in one of the phases – of course, this book focuses on the aqueous phase. It is this catalyst recycling, together with the much simplified technology, where the interest of the chemical industry lies. Small scale laboratory procedures may also benefit from using organometallic catalysts in aqueous solutions due to the easier, cleaner isolation of the desired products of biphasic reactions. In addition, growing environmental concern forces industry and research laboratories to use less and less environmentally hazardous chemicals, and water –as opposed to most organics– is certainly an environmentally benign (green) solvent. A somewhat less obvious and less exploited possibility is in that several catalytic reactions which do take place in homogeneous aqueous solutions or in biphasic systems simply do not happen in dry organic solvents.

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